Study of the catalytic activity of non-heme manganese complexes toward oxidation of cyclooctene and cyclohexene

Applied Catalysis A: General(2014)

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摘要
•Oxidation reaction of cyclohexene using a manganese-complex as catalyst showed selectivity of 91% for the epoxide.•EPR investigation of intermediates showed active species possibility contains MnIII.•MnIII–MnIV species are inactive.•Heptacoordination versus hexacoordination.
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关键词
Non-heme,Manganese,Catalysis,Oxidation,EPR
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