ChemInform Abstract: Ring Opening of Cyclic Sulfamidates with Magnesiated Heterocycles: Expedient Synthesis of Highly Functionalized Azaindolines and Azatetrahydroquinolines.

Thomas A Moss,Barry R Hayter,Ian A Hollingsworth,Thorsten Nowak

Cheminform（2013）

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摘要

Azaindolines (III) and azatetrahydroquinolines (V) are prepared in a stereo-predictable manner via ring opening of cyclic sulfamidates with metalated chloro heterocycles, followed by intramolecular cyclization upon basification of the adducts.

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azatetrahydroquinolines,magnesiated heterocycles,cyclic sulfamidates,azaindolines,cheminform abstract

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