Surface excess amounts in high-pressure gas adsorption: Issues and benefits

Jean Rouquerol,F Rouquerol,P L Llewellyn,Renaud Denoyel

Colloids and Surfaces A: Physicochemical and Engineering Aspects（2016）

引用 9|浏览11

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摘要

•The dead volume issue in high pressure gas adsorption is carefully examined.•The usual Gibbs representation is modified for adsorption by microporous adsorbents.•The concept of “Gibbs exclusion volume” is proposed for a safe data reporting.•Case study: how to improve an inter-laboratory comparison of adsorption data.

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关键词

Gibbs adsorption model,Gibbs exclusion volume,Amount adsorbed,Surface excess amount,Dead space,Buoyancy correction

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