Anomalies of some physical properties and electrochemical performance of lithium–lead–germanate glasses

Journal of Non-Crystalline Solids(2012)

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摘要
The purpose of this paper was to approach the structure–properties interrelationship of lithium–lead–germanate glasses in order i) to understand the structural mechanism responsible for the germanate anomaly; ii) to determine some physical properties such as density, optical gap energy, refractive index; iii) to find electrochemical performance of the studied glasses. The studied homogeneous glass system has the xLi2O·(100−x)·[7GeO2·3PbO] composition where 0≤x≤40mol%Li2O.
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关键词
Lithium–lead–germanate glasses,FTIR and UV–VIS spectroscopy,DFT calculations
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