New chiral ligands derived from (+) and (-)-α-pinene for the enantioselective addition of diethylzinc to aldehydes

Gustavo Frensch,Ricardo Labes,Celso L Wosch,Laieli Dos Santos Munaretto,Kahlil S Salome,Palimecio G Guerrero,Francisco A Marques

Tetrahedron Letters（2016）

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摘要

In this study, we synthesized five new chiral ligands from (+) and (−)-α-pinene, which were successfully employed in the stereoselective addition of diethylzinc to aldehydes, leading to secondary chiral alcohols in up to 99% yield and 94% e.e.

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BCDMPBIHYVTOMY-FMSGJZPZSA-N,OTBXPRJLIYBQHF-SNVBAGLBSA-N,BBHSZOOWHIJKLU-XPCVCDNBSA-N,JRQTWVSBROAISM-FMSGJZPZSA-N,WKWGHWACXXWYHD-FMSGJZPZSA-N,WMPDAIZRQDCGFH-UHFFFAOYSA-N

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