Asterolloside, a novel enolic saccharide from the sea star Asterias rollestoni Bell

Xianwen Yang,Zi Miao, Xiaoni Ma,Gaiyun Zhang,Andre Steinmetz,Bin Yang,Junfeng Wang,Juan Liu,Yonghong Liu,Ning Wang

Tetrahedron Letters（2015）

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摘要

•Isolation of a novel enolic saccharide named asterolloside.•Asterolloside is the first example of natural enolic glycoside.•Structure elucidation is achieved mainly by analysis of NMR spectroscopic data.•Absolute structure was established by Cu-Kα X-ray crystallography.

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关键词

Starfish,Asterias rollestoni,Enolic saccharides,α-Glucosidase

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