Organometallic chemistry of extended periodic π-electron systems: hexahapto-chromium complexes of graphene and single-walled carbon nanotubes

CHEMICAL SCIENCE, no. 7 (2011): 1326-1333

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We explore the organometallic chemistry of graphitic materials and demonstrate the eta(6)-complexation reactions of chromium with graphene, graphite and carbon nanotubes. All of these extended periodic pi-electron systems exhibit some degree of reactivity toward the reagents Cr(CO)(6) and (eta(6)-benzene) Cr (CO)(3), and we are able to de...更多

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