Regioselective Dye-Induced Photocleavage Of Epoxides As An Alternative Mild Synthetic Route To A Targeted Alcohol Functionality

Anthony A Provatas,Gary A Epling,James D Stuart,Aliaksandr Yeudakimau

AUSTRALIAN JOURNAL OF CHEMISTRY（2015）

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摘要

The regioselective cleavage of epoxides using visible light and a catalytic dye is reported in this study as an alternative mild synthetic approach. The epoxide radical anion is generated via visible light in an electron transfer reaction, induced by non-toxic dyes, leading to ring opening and formation of the corresponding alcohol with the hydroxyl group on the less substituted carbon in excellent yields.

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关键词

crystallography,organic chemistry,pharmaceutical chemistry,proteins,crystal structures,reaction mechanisms,spectroscopy,macromolecules,medicinal chemistry,photochemistry,structure,biological chemistry,electrochemistry,mass spectrometry,supramolecular chemistry,combinatorial chemistry,polymer chemistry,analytical chemistry,combinatorial,surface chemistry,biocatalysis,kinetics,catalysis,educational,computational chemistry,biosensors,colloids,green chemistry,quantum chemistry,self assembly,density functional theory,amino acids,physical chemistry,ab initio calculations,nanotechnology,enzymes,interfaces,ionic liquids,peptide,inorganic chemistry,sensors

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