Multiple Noncovalent Bonding In Halogen Complexes With Oxygen Organics. I. Tertiary Amides
JOURNAL OF PHYSICAL CHEMISTRY A(2016)
摘要
The present work describes the structure and binding of adducts of N,N'-diacetylpiperazine with halogens and interhalogens based on combination of different experimental methods and quantum chemical calculations. On the basis of conductometric and spectro-photometric experimental results, behavior of complexes in the acetonitrile solution was described. The iodine adduct with N,N'diacetylpiperazine fully degrades into components. Adducts of interhalogens I-X (X = Cl or Br) with N,N'diacetylpiperazine in acetonitrile partially dissociate to anionic [X-I-X](-) and cationic species. In the solid state, molecules are connected via C=O center dot center dot center dot I, C-H center dot center dot center dot I, and Cl center dot center dot center dot Cl attractive interactions. N,M-diacetylpiperazine-dihalogen complex is stabilized by simultaneous C=O center dot center dot center dot I and C-H center dot center dot center dot I interactions. Such binding mode allows to explain the problems of the direct halogenation of acetyl-containing compounds with molecular halogens as reagents. We believe that the observed binding pattern can be used as prototypical for future design of halogeno complexes.
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