Study of degradation mechanism of dechlorane plus by mechanochemical reaction with aluminum and quartz sand

Haizhu Wang,Jun Huang,Siyu Zhang,Ying Xu,Kunlun Zhang,Kai Liu, Zhiguo Cao,Gang Yu,Shubo Deng,Yujue Wang,Bin Wang

Chemical Engineering Journal（2016）

引用 20|浏览26

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摘要

•Mechanochemical destruction of DP was prompted by Al and quartz sand.•Main solid products include carbon, AlCl3·6H2O, silicon etc.•Main gaseous products include H2, CH4, C2H6, C2H4 etc.•Thermite-type reaction and dechlorination followed by carbonization are mechanism.

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关键词

Mechanochemical destruction,Dechlorane plus,Quantum chemical calculations,Thermite-type reaction

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