Metal-Based Diversity for Crystalline Metal-Fullerene Frameworks.
CHEMISTRY-A EUROPEAN JOURNAL(2017)
摘要
Four different three-dimensional metal-fullerene frameworks were synthesized through polymerization of two C-60-derived dodecaacids with varying alkyl spacers in the presence of Ca2+, Cu2+ or Cd2+ ions. Structural analysis of the frameworks was performed by single-crystal Xray diffraction and porosity of the materials was investigated by sorption measurements.
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关键词
cadmium,calcium,copper,fullerenes,metal-organic frameworks
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