Nickel-catalyzed Reductive Etherification of Aldehydes at Room Temperature: C-O vs. C-C Bond Formation.

Sajjad Rahimi,Farhad Panahi,Marzieh Bahmani,Nasser Iranpoor

JOURNAL OF ORGANIC CHEMISTRY（2018）

引用 8|浏览6

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摘要

The reaction of secondary and tertiary benzyl alcohols activated by 2,4,6-trichloro-1,3,5-triazine (TCT) with aldehydes in the presence of NiCl2-dmg as a precatalyst in ethylene glycol afforded ethers at room temperature. A selective C-O vs C-C bond formation was observed for the secondary and tertiary benzyl alcohols in comparison with primary ones.

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