Titanium(Iii) Member Of The Family Of Trigonal Building Blocks With Scorpionate And Cyanide Ligands

Andrew Brown,Mohamed Saber,Willem Van den Heuvel, Kelsey Schulte,Alessandro Soncini,Kim R Dunbar

INORGANIC CHEMISTRY（2017）

引用 12|浏览8

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摘要

The titanium(III) cyanide compound [Et4N] [Tp*Ti(CN)(3)] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.

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