[3 + 3] Cycloaddition of Azides with in Situ Formed Azaoxyallyl Cations to Synthesize 1,2,3,4-Tetrazines
Organic letters(2018)
摘要
A formal [3 + 3] cycloaddition reaction between azides and in situ formed azaoxyallyl cations has been realized. This reaction provided an efficient and practical pathway to synthesize 1,2,3,4-tetrazines in good yields under mild conditions. Biologically active molecules could also be well compatible, highlighting the potential value of this reaction.
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