Visible-Light-Promoted Oxidative Amidation of Bromoalkynes with Anilines: An Approach to α‑Ketoamides

Organic Letters(2018)

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摘要
A convenient and practical synthetic route to α-ketoamides from bromoalkynes and anilines through phototriggered organic transformations via a C–N cross-coupling and an oxidation of C≡C was developed. The reaction could be furnished without an external photocatalyst at ambient conditions, and a wide range of α-ketoamides were obtained in good yields.
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