Self-assembly and ring-opening metathesis polymerization of cyclic conjugated molecules on highly ordered pyrolytic graphite.
CHEMICAL COMMUNICATIONS(2018)
摘要
Cyclic conjugated monomers comprising cyclopentadithiophenevinylene trimers and their polymers on HOPG are observed using STM and AFM. ROMP of the monomers is performed using a Grubbs catalyst. Their STM images exhibit single chains of planar polymers, whereas their AFM images show elongation of the polymer chains on HOPG.
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