Dual electrical switching permeability of vesicles via redox-responsive self-assembly of amphiphilic block copolymers and polyoxometalates.
CHEMICAL COMMUNICATIONS(2018)
摘要
Electro-responsive vesicles were demonstrated based on an amphiphilic block copolymer PEO114-b-P(DCH-Ru)(n) and an inorganic nanoparticle polyoxometalate H3PMo12O40 (PMo12) via electrostatic interactions. After undergoing electrochemical reactions, vesicle membranes allow the migration of electrolyte ions and release of loaded cargos.
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