Abrupt Thermal Shock of (NH 4 ) 2 Mo 3 S 13 Leads to Ultrafast Synthesis of Porous Ensembles of MoS 2 Nanocrystals for High Gain Photodetectors.

Ultrafast synthesis of high quality transition metal dichalcogenide (TMDQ) nanocrystals such as molybdenum disulfide (MoS2) is technologically relevant for large-scale production of electronic and optoelectronic devices. Here, we report a rapid solid-state synthesis route for MoS2 using the chemically homogeneous molecular precursor, (NH4)2Mo3S13·H2O, resulting in nanoparticles with estimated size down to 25 nm only in 10 sec at 1000 oC. Despite the extreme non-equilibrium conditions, the resulting porous MoS2 nanoparticles remain aggregated to preserve the form of the original rod shape bulk morphology of the molecular precursor. This ultrafast synthesis proceeds through the rapid decomposition of the precursor and rearrangement of Mo and S atoms coupled with simultaneous efficient release of massive gaseous species, to create nanoscale porosity in the resulting isomorphic pseudocrystals which are composed of the MoS2 nanoparticles. Despite the very rapid escape of massive amounts of NH3, H2O, H2S and S gases from the (NH4)2Mo3S13·H2O mm sized crystals, they retain their original shape as they convert to MoS2 rather than undergo explosive destruction from the rapid escape process of the gases. The obtained pseudocrystals are made of aggregated MoS2 nanocrystals exhibit a Brunauer-Emmett-Teller (BET) surface area of ~35 m2/g with an adsorption average pore width of ~160 Å. The nanoporous MoS2 crystals are solution-processable by dispersing in ethanol and water and can be cast into large-area uniform composite films. Photodetectors fabricated from these films show more than two orders of magnitude higher conductivity (~6.25 × 10-6 S/cm) and photoconductive gain (20 mA/W) than previous reports of MoS2 composite films. The optoelectronic properties of this nanoporous MoS2 imply that the shallow defects that originate from the ultrafast synthesis act as sensitizing centers that increase the photocurrent gain via two-level recombination kinetics.