Highly regioselective hydroxylation of polydatin, a resveratrol glucoside, for one-step synthesis of astringin, a piceatannol glucoside, by P450 BM3.
Enzyme and Microbial Technology(2017)
摘要
•A set of CYP102A1 mutants can catalyze regioselective hydroxylation of polydatin.•Major product of polydatin hydroxylation is astringin, a piceatannol glucoside.•An efficient enzymatic synthesis of astringin, a piceatannol glucoside, was developed.
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关键词
NADPH,p-NP,P450 or CYP,TTN,WT
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