Role Of Phosphine Sterics In Strained Aminophosphine Chelate Formation

INORGANIC CHEMISTRY(2019)

Cited 16|Views42
No score
Abstract
The preparation of four-membered aminophosphine (PN) chelates from common metal precursors has largely evaded realization because of the ring strain associated with these species. We report a straightforward approach to the synthesis of such PN metallacycles using simple alpha-PN ligands analogous to the popular class of small-bite-angle diphosphinomethane ligands. It is demonstrated that bulky phosphine substituents are important to the formation of these chelates.
More
Translated text
Key words
phosphine sterics
AI Read Science
Must-Reading Tree
Example
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined