[bmIm]OH-catalyzed amidation of azides and aldehydes: an efficient route to amides
GREEN CHEMISTRY(2016)
摘要
A [bmIm]OH-catalyzed amidation of azides and aldehydes is reported. This reaction is easily handled and proceeds under mild conditions. The overall transformation involves azide-enolate cycloaddition, which subsequently undergoes rearrangement to give amides. Importantly, the employment of ionic liquid makes this transformation green and practical.
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