Effect of Zn2+ Substituted On Structural and Magnetic Properties of Manganese Ferrite Synthesized Via Combustion Route
ADVANCED SCIENCE LETTERS(2016)
摘要
Solution combustion method was successfully used for the synthesis of nanocrystalline Mn1-xZnxFe2O4 with stoichiometry (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1.0). The room temperature dielectric studies real and imaginary part of permittivity (epsilon' and epsilon ") were undertaken in the vide frequency range 1 MHz to 1 GHz. It was found that the real part of permittivity (epsilon') is increases with increasing in frequency and it shows a resonance behavior above 1 GHz and at much higher frequencies there is a significant decrease in the loss factor (epsilon "). The magnetic domain relaxation was investigated by inductance spectroscopy (IS) and the observed magnetic domine relaxation frequency (f(r)) was increased with increase of grain size. It was observed that the real and imaginary part of permeability (mu' and mu "), saturation magnetization (M-s), remnant magnetization (M-r) and magneton number decreases gradually with increasing Zn2+ concentration. The decrease in the saturation magnetization may be explained as the Zn2+ concentration increases, the relative number of ferric ions on the A sites diminishes and this reduces the A-B interaction.
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关键词
Ferrites,Solution Combustion Route,Permittivity,Permeability,Magneton Number
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