Synthesis of PAMAM dendrimers with porphyrin core and functionalized periphery as templates of metal composite materials and their toxicity evaluation
Arabian Journal of Chemistry(2020)
摘要
Experiments were performed for the synthesis of meso-substituted tetraphenyl porphyrins in order to obtain growth active points for PAMAM branches and a functionalized periphery with thiazole groups for increasing the metal complexation activity. Characterization by 1H and 13C NMR, mass spectrometry and infrared spectrometry confirmed the produced dendrimeric nanostructures; the chemical reduction of metallic Ag and Cu inside the dendrimer was proved by XPS. Finally, the toxicity of the metal-dendrimer complex was analyzed by means of the bacterial respiration test.
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关键词
Porphyrin,PAMAM-dendrimers,Metal complex,Metal species
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