Total Synthesis of Xestoaminol C from D-Glucose

Hanmanth Reddy Vulupala,Yasodakrishna Sajja,Rajashaker Bantu,Lingaiah Nagarapu

CURRENT ORGANIC CHEMISTRY（2015）

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摘要

A convenient and practical approach for the total synthesis of Xestoaminol C has been accomplished with 16.43% overall yield from commercially available D-glucose. The synthesis involves S(N)2 type centre inversion with azido group, Staudinger reaction, Wittig olefination and Pearlman's catalytic hydrogenation.

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关键词

Staudinger reaction,Wittig olefination,oxidative cleavage,hydrogenation,D-glucose

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