Coordination capabilities of metal ions and steric features of organic ligands affecting formation of mono- or binuclear zinc(II) and cadmium(II) pivalates

Stanislav A. Nikolaevskii,Igor S. Evstifeev,Mikhail A. Kiskin,Alyona A. Starikova,Alexander S. Goloveshkin,Valentin V. Novikov,Natalya V. Gogoleva,Alexey A. Sidorov,Igor L. Eremenko

Polyhedron（2018）

引用 26|浏览20

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摘要

Reactions between zinc(II) or cadmium(II) pivalates and 2,2′-bipyridine, various substituted 1,10-phenanthroline derivatives have resulted in ten mono- and binuclear complexes. Preferable formation of binuclear cadmium compounds depending on type of the ligand are studied and clearly explained by means of DFT calculations.

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关键词

Zinc complexes,Cadmium complexes,Carboxylate complexes,Single crystal X-ray diffraction,Luminescence

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