Studies on Interfacial Tensions of Ionic Surfactant and Alkyl Sulfobetaine Mixed Solutions

To expound the mechanisms responsible for reducing interfacial tensions (IFTs) in amphoteric and ionic surfactant mixed systems, the IFTs of mixed solutions containing alkyl sulfobetaine (ASB) and different ionic surfactants against hydrocarbons with different carbon numbers have been investigated by the spinning drop method. For cationic surfactants, the antagonistic effect for reducing IFT appears between cationic and ASB molecules because of electrostatic repulsion, which results in competitive adsorption. On the other hand, the synergistic effect will be observed in ionic and ASB mixed systems as a result of the mixed adsorption caused by the electrostatic attraction. The "chain length compatibility" between the anionic surfactant and ASB molecules leads to a stronger synergistic effect and further reduces IFT. However, "size compatibility" plays the crucial role, and only mixed solutions containing an anionic surfactant with a larger hydrophobic group can produce ultralow IFT against hydrocarbons. The strong synergistic effect among ASB, ionic surfactant, and natural surface-active materials will produce ultralow IFTs against crude oil during wider concentration ranges compared to ASB solution, which is very meaningful for the application of betaines in enhanced oil recovery.