Mechanistic study on the hydrolytic degradation of polyphosphates

Kristin N. Bauer,Lei Liu,Manfred Wagner,Denis Andrienko,Frederik R. Wurm

European Polymer Journal（2018）

引用 44|浏览7

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摘要

•Acidic and basic hydrolysis of water-soluble polyphosphoesters.•NMR characterization of degradation products and degradation kinetics.•Backbiting mechanism for poly(alkyl ethylene phosphate)s proven.•Blocking of terminal OH-groups slows down hydrolysis.

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