Studies on the structural diversity of MOFs containing octahedral siloxane-backboned connectors

Luke C. Delmas,Peter Horton,Andrew J. P. White,Simon J. Coles,Paul D. Lickiss,Robert P. Davies

Polyhedron（2019）

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摘要

The siloxane-based linker hexakis(4-carboxyphenyl)disiloxane (L-H6) has been used in the construction of four 3D MOFs via treatment with Cd2+, Ce3+, Y3+ and Zn2+ salts. The underlying nets in these MOFs have been evaluated through deconstruction of their crystal structures and subsequent topological analysis.

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关键词

Siloxane,Polytopic linkers,MOFs,Metal–organic frameworks,Hybrid materials

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