Evolution of nascent mantle wedges during subduction initiation: Li-O isotopic evidence from the Luobusa ophiolite, Tibet

The Li-O isotopes of olivine and pyroxene from the mantle sequence of the Luobusa ophiolite, a fragment of Neo-Tethyan forearc lithosphere in Tibet, reveal a series of magmatic processes and geochemical evolution in a nascent mantle wedge during subduction initiation. Olivine grains from the ophiolitic mantle sequence display δ18O values similar to those of normal mantle (+5.18 ± 0.2‰), but have large δ7Li variations, ∼+4‰ to +13‰ in harzburgites and ∼+1‰ to +11‰ in high-Cr chromitites. Clinopyroxene grains in cpx-bearing harzburgites have finger-like protrusions and LREE-depleted patterns comparable to those of clinopyroxene in abyssal peridotites, and also show high Li concentrations (∼2–8 μg/g) and negative δ7Li values (∼−15‰ to −8‰), which are beyond the ranges of normal upper mantle (<1.3 μg/g and +4 ± 2‰, respectively). Our dataset suggests that the nascent Luobusa harzburgitic mantle wedge was penetrated by limited amounts of slab-derived fluids at an early stage, leading to decoupling of high δ7Li but normal mantle-like δ18O values of the mantle rocks. The hydrated harzburgites were later refertilized by depleted mantle-derived melts. This process generated the cpx-bearing harzburgites with light-δ7Li clinopyroxene, and also imposed normal mantle-like Li isotopic signatures on some previously hydrated high-δ7Li mantle areas at deeper levels. Subsequent melting in both the high-δ7Li and normal mantle-like Li isotopic mantle regimes generated the parental magmas of the high-Cr chromitites with high-Ca boninitic affinities, accounting for the large δ7Li variation of olivine in the chromitites. Slab rollback below the nascent mantle wedge induced asthenospheric upwelling and a high geothermal gradient, which played a more direct role than slab dehydration in triggering the magmatic events of refertilization and formation of the high-Cr chromitites. Numerical modeling of inter-mineral Li diffusion in cpx-bearing harzburgites suggests an interval of <1000 years between the two magmatic events and rapid slab rollback before the generation of the high-Cr chromitites. Intra-oceanic emplacement of the Luobusa proto-forearc lithosphere was possibly finished within 106 years after the chromitite formation.