Synthesis of glaucogenin D, a structurally unique disecopregnane steroid with potential antiviral activity.
ORGANIC LETTERS（2013）
摘要
The first chemical synthesis of glaucogenin D, a 13,14:14,15-disecopregnane steroid with potential antiviral activity, has been accomplished in 12 steps from a hirundigenin-type intermediate. The present route would also be amenable to the synthesis of natural and unnatural glaucogenin derivatives for SAR studies.
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