Organocatalytic Synthesis of Sulfoximidoyl-Containing Carbamates from Sulfoximines and Morita–Baylis–Hillman Carbonates
Organic Letters(2019)
摘要
An unexpected substitution reaction providing sulfoximidoyl-containing carbamates was observed when Morita–Baylis–Hillman carbonates and NH-sulfoximines were mixed in acetonitrile at elevated temperature. Key ingredients were triethylamine and ortho-hydroxybenzoic acid, which both had to be present in catalytic quantities.
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