Mechanism of Electroless Copper Deposition from [CuIIEDTA]2– Complexes Using Aldehyde-Based Reductants

Journal of Physical Chemistry C, pp. 24789-24793, 2016.

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Abstract:

In this article, we present a mechanism for electroless copper deposition from alkaline solutions containing [CuIIEDTA]2–(aq) and hydrolyzed aldehydes. The mechanism is based on quantum chemical calculations of the activation energies and reversible electron-transfer potentials. Low-coordinated, electroless-deposited surface Cu atoms are ...More

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