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Structurally Diverse Boron-Nitrogen Heterocycles from an N2O23− Formazanate Ligand

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, no. 28 (2017): 8173-8177

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Five new compounds comprised of unprecedented boron-nitrogen heterocycles have been isolated from a single reaction of a potentially tetradentate N2O23- formazanate ligand with BF3 center dot OEt2 and NEt3. Optimized yields for each product were obtained through variation of experimental conditions and rationalized in terms of relative Gi...更多

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