Di- and trivalent chromium bis(pyrazol-3-yl)pyridine pincer complexes with good leaving groups
Inorganica Chimica Acta(2019)
摘要
•Coordination of bis(pyrazol-3-yl)pyridine pincer ligand to Cr(II) and Cr(III)•CV and DFT calculations conclude that methylated pincer ligand is redox-active.•Nitrate is shown to be a stronger ligand than triflate.•Cr(II) complexes here show Jahn-Teller distortion.
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关键词
Divalent chromium,Trivalent chromium,Pincer,Proton responsive ligand,Nitrate,Triflate
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