Understanding the redox reaction mechanism of vanadium electrolytes in all-vanadium redox flow batteries
Journal of Energy Storage(2019)
摘要
•The electrochemical analysis and simulation are described to understand mechanism.•The Rct of the negative electrode is sensitive to heat treatment and temperature.•There are hydration structure difference between vanadium ion and water molecules.
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关键词
Vanadium redox flow battery,Impedance analysis,Symmetric cell,Inner sphere mechanism,Outer sphere mechanism
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