Dibutyl phosphate catalyzed commercial relevant ring-opening polymerizations to bio-based polyesters

Jingjing Liu,Chan Zhang,Zhenjiang Li,Lei Zhang,Jiaxi Xu,Haixin Wang,Songquan Xu,Tianfo Guo,Kun Yang,Kai Guo

European Polymer Journal（2019）

引用 16|浏览5

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摘要

•A commercial DBuP was firstly evaluated as catalyst for ROP in bulk at 180 °C.•Polyesters of narrow dispersity and high molecular weight were obtained.•Diblock copolymers, end functionalized polyesters, and star polymers were prepared.•Cell viability of DBuP-catalyzed PCL meets biomedical requirements.

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关键词

Organocatalyst,Phosphoric acid,Polyesters,Ring-opening polymerization

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