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Enhanced direct deoxygenation of anisole to benzene on SiO2-supported Ni-Ga alloy and intermetallic compound

Applied Catalysis B: Environmental(2019)

Cited 64|Views4
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Abstract
•Ga geometrically and electronically modify Ni in Ni-Ga alloy and IMC.•Direct deoxygenation (DDO) was more preferential on Ni-Ga alloy and IMC than Ni.•Benzene hydrogenation, CC cleavage and methanation was suppressed on alloy and IMC.•H2 was generated from anisole via methanol decomposition on Ni-Ga alloy and IMC.•There was a synergetic effect between Ni and Ga on alloy and IMC for HDO.
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Key words
Ni-Ga alloy and intermetallic compound,Hydrodeoxygenation,Hydrogenation,CC hydrogenolysis,Methanation
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