Electron Doping BaZrO 3 via Topochemical Reduction

Thomas Orvis
Thomas Orvis
Mythili Surendran
Mythili Surendran
Yang Liu
Yang Liu
Shanyuan Niu
Shanyuan Niu
Shin Muramoto
Shin Muramoto
Alexander J Grutter
Alexander J Grutter

ACS applied materials & interfaces, Volume 11, Issue 24, 2019, Pages 21720-21726.

Cited by: 0|Bibtex|Views0|DOI:https://doi.org/10.1021/acsami.9b06370
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Other Links: pubmed.ncbi.nlm.nih.gov|academic.microsoft.com

Abstract:

We report the topochemical reduction of epitaxial thin films of the cubic perovskite BaZrO. Reduction with calcium hydride yields n-type conductivity in the films, despite the wide bandgap and low electron affinity of the parent material. X-ray diffraction studies show concurrent loss of out-of-plane texture with stronger reducing conditi...More

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