Tandem Approach to Functionalized Pyrrolo[3,4- a ]carbazole-1,3-diones via a Pd-catalyzed Indole-to-carbazole Transformation

Lianghua Guo,Mei Xu,Yong Jian,Sheng Liu,Weidong Pan,Lian Duan

Chemical Research in Chinese Universities（2019）

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摘要

A one-pot and efficient three-component reaction of indoles, acrylates and maleimides for the synthesis of pyrrolo[3,4- a ]carbazole-1,3-dione derivatives was developed. Theree C-C bonds and one ring were created in a single step via an indole-to-carbazole transformation triggered by Pd(II)-catalyzed direct C3-alkenylation of indoles.

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关键词

Carbazole, One-pot, Tandem reaction, Three-component reaction, Indole-to-carbazole

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