Axially Chiral N,N '-Dioxides Ethers For Catalysis In Enantioselective Allylation Of Aldehydes
CHIRALITY(2019)
摘要
A series of axially chiral ethers synthesized from biscarboline N,N '-dioxides, (S)-1a to (S)-1n, was investigated in enantioselectivity addition reactions of allyltrichlorosilane with a series of substituted aldehydes, including bulky substituted aldehydes. High enantioselectivities (up to 96%ee) were achieved using the catalyst (S)-1k at 1 mol % loading.
更多查看译文
关键词
axially chiral biscarboline ethers,enantioselective allylation,N,N '-dioxides
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要