Multi-peak Electronic Density of States in CrBr3 Revealed by Scanning Tunneling Microscopy

CrBr3 is a layered van der Waals material with magnetic ordering down to the 2D limit. So far, the electronic properties of CrBr3 are relatively unexplored. Here, we present the scanning tunneling microscopy and spectroscopy (STM/S) results of the CrBr3 thin flakes exfoliated onto a Highly Ordered Pyrolytic Graphite (HOPG) surfaces. Atomic resolution topography images show the crystal structure and the dI/dV spectra exhibit multiple peak features measured at 77 K. The conduction band - valence band peak pairs in the multi-peak dI/dV spectrum agrees very well with all the reported optical transitions in literature. The density of states (DOS) calculated by the density functional theory (DFT) agrees qualitatively with the experimental dI/dV spectrum, except two small peaks near the Fermi energy. The flake degradation is found at the edges of the mono- and bi-layer flakes. The results shown here pave the way toward the fundamental understanding of the CrBr3.