Palladium-Catalyzed Double Substitution of 3-Aryl-2-fluoroallyl Acetates with Phenols via C–F Bond Activation

Eito Nomada,Hirotaka Watanabe,Mitsuaki Yamamoto,Takumi Udagawa,Biao Zhou,Akiko Kobayashi,Maki Minakawa,Motoi Kawatsura

SYNLETT（2014）

引用 20|浏览9

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摘要

The double substitution of 3-aryl-2-fluoroallyl acetates with phenols has been accomplished; the Pd(PPh3)(4) catalyst system has effectively catalyzed the reaction to afford the doubly substituted product via carbon-fluorine bond activation.

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关键词

palladium,catalysis,fluorine,phenols,coupling

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