Associative intraligand substitution of anticancer azolato-bridged compounds without a square-pyramidal intermediate: Formation of a unique tetranuclear, µ3-1,2,3-triazolato-N1,N2,N3-bridged Pt(II) compound

Seiji Komeda,Yasuko In,Koji Tomoo,Katsuhiko Minoura,Takaji Sato,Jan Reedijk,Toshimasa Ishida,Masahiko Chikuma

Inorganica Chimica Acta（2019）

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摘要

•Unusual intraligand substitution of N3 for N2 of 1,2,3-triazolate.•Pt(II) migration related to the mechanism of action of the dinuclear Pt(II) compounds.•Dimerization reaction to yield a unique tetranuclear Pt(II) compound.•Presented importance of 1,2,3-triazolate derivatives as a tridentate building block.

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关键词

unique tetranuclear,compounds,associative intraligand substitution,azolato-bridged,square-pyramidal

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