Application of Cold Region Regenerable Biomass in Phosphorus Adsorption in Reclaimed Water

In order to enhance the using efficiency of the adsorbent and decrease production costs, reclaimed saturation Lanthanum modified pine needles (LH pine needles) have been studied as a possible solution. Pine needles gathered from the woods of Northeast China area were used as raw material for generating LH pine needles by alkali-isopropanol treatment and chemical precipitation. To explore the utilization of LH pine needles as a recycling adsorbent in wastewater treatment plants (WWTPs) and laboratory water distribution. Results show that removal effective of phosphorus (P) by LH pine needles in low concentration reclaimed water of WWTPs was 41% and up to more than 92% in its adding standard. In the wide pH range, LH pine has an effective adsorption capacity for phosphorus; pH can also interfere with the adsorption capacity of LH pine as there is a negative correlation between them. The adsorption of phosphorus by LH pine needles is divided into three stages with a pH ranging from 3~11. Ligand exchange reaction, electrostatic reaction and Lewis acid reaction are PO43− adsorption mechanism. The analysis of the recycling efficiency of LH pine needles proved that LH pine needles have good regeneration performance. After being eluted by NaOH regeneration agent for more than 10 times, the adsorption efficiency of phosphorus can still be stable at over 90% in seven cycles.