Development Of Use-Specific High-Performance Cyber-Nanomaterial Optical Detectors By Effective Choice Of Machine Learning Algorithms

Due to their inherent variabilities, nanomaterials-based sensors are challenging to translate into real-world applications, where reliability and reproducibility are key. Machine learning can be a powerful approach for obtaining reliable inferences from data generated by such sensors. Here, we show that the best choice of ML algorithm in a cyber-nanomaterial detector is largely determined by the specific use-considerations, including accuracy, computational cost, speed, and resilience against drifts and long-term ageing effects. When sufficient data and computing resources are provided, the highest sensing accuracy can be achieved by the k-nearest neighbors (kNNs) and Bayesian inference algorithms, however, these algorithms can be computationally expensive for real-time applications. In contrast, artificial neural networks (ANNs) are computationally expensive to train (off-line), but they provide the fastest result under testing conditions (on-line) while remaining reasonably accurate. When access to data is limited, support vector machines (SVMs) can perform well even with small training sample sizes, while other algorithms show considerable reduction in accuracy if data is scarce, hence, setting a lower limit on the size of required training data. We also show by tracking and modeling the long-term drifts of the detector performance over a one year time-frame, it is possible to dramatically improve the predictive accuracy without any re-calibration. Our research shows for the first time that if the ML algorithm is chosen specific to the use-case, low-cost solution-processed cyber-nanomaterial detectors can be practically implemented under diverse operational requirements, despite their inherent variabilities.