Controlled Growth and Bandstructure Properties of One Dimensional Cadmium Sulfide Nanorods for Visible Photocatalytic Hydrogen Evolution Reaction.

One dimensional (1D) metal sulfide nanostructures are one of the most promising materials for photocatalytic water splitting reactions to produce hydrogen (H-2). However, tuning the nanostructural, optical, electrical and chemical properties of metal sulfides is a challenging task for the fabrication of highly efficient photocatalysts. Herein, 1D CdS nanorods (NRs) were synthesized by a facile and low-cost solvothermal method, in which reaction time played a significant role for increasing the length of CdS NRs from 100 nm to several micrometers. It is confirmed that as the length of CdS NR increases, the visible photocatalytic H-2 evolution activity also increases and the CdS NR sample obtained at 18 hr. reaction time exhibited the highest H-2 evolution activity of 206.07 mu mol.g(-1).h(-1). The higher H-2 evolution activity is explained by the improved optical absorption properties, enhanced electronic bandstructure and decreased electron-hole recombination rate.