Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant

Bing Qi,Lili Fang,Qi Wang,Shan Guo,Pengfei Shi,Benfa Chu,Jin Zhu

Tetrahedron Letters（2020）

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摘要

•First time use of N-Cl bond as an internal oxidant for isoquinoline.•Atom- and step-economic synthesis in a green solvent.•Under a mild condition with a broad substrate scope.•High coordinating and oxidizing reactivity.

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关键词

CH functionalization,Isoquinoline,N–Cl bond,Internal oxidant

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