Catalytic upgrading of Kraft lignin derived bio-oil in supercritical ethanol over different crystal size hierarchical nano-HZSM5
Fuel(2020)
摘要
•Reduction in HZSM5 crystal size enhanced the catalytic performance.•Alkylated guaiacols were the major compounds obtained upon bio-oil upgrading.•HHV value increased from 27.03 to 30.85 MJ/Kg upon bio-oil upgrading over HZSM5-375.•Tetrahedral Al atoms were lost from the zeolite framework after bio-oil upgrading.•Decline in the Al content reduced the catalytic performance of HZSM5-375.
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关键词
Upgrading,Bio-oil,HZSM5,Kraft lignin,Hierarchical
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