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Crystal Structure Ofn′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide Monohydrate

Acta crystallographica Section E, Crystallographic communications(2020)

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摘要
The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C14H15N3O2·H2O. The crystal packing is stabilized by intermolecular O(water)—H...O,N(carbohydrazide) and N—H...O(water) hydrogen bonds, which form a two-dimensional network along thebcplane. Additional C—H...O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety,i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes.
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关键词
crystal structure,hydrazide,hydrazone,furoic acid
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