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Copper‐Catalyzed Ortho‐thiomethylation of Benzamides Via 8‐aminoquinoline‐assisted C‐H Activation with Dimethyl Sulfoxide

Xinfeng Cui,Xingxing Liu,Xiajun Wang,Wanfa Tian,Daidong Wei,Guosheng Huang

ChemistrySelect（2017）

Cited 11|Views4
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Abstract
An efficient and facile protocol concerning Cu(II)-catalyzed methylthiolation of 8-aminoquinoline amides under air atmosphere with widely available DMSO as the terminal thiomethyl source has been developed. The reaction exhibits excellent functional group tolerance and highly regioselectivity, which provides an attractive approach for aryl methyl thioethers preparation.
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Key words
aminoquinoline amides,C-H activation,copper,dimethyl sulfoxide (DMSO),methylthiolation
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